Using a large sample of smokers (N = 1592, 53% female, 84% Caucasian) who volunteered to take part in a smoking cessation intervention, responses to 12 “indicator” items collected from a social network interview were analyzed utilizing finite mixture modeling (FMM). In order to prevent biased parameter estimates and the overextraction of mixture components from non-normal data, mixtures of multivariate t-distributions were used as a robust alternative to the traditional Gaussian mixture model (e.g. Model-Based Clustering, Latent Class Cluster Analysis, MCLUST). Six latent clusters were identified and revealed an underlying structure composed of significantly different social network sub-groups within the sample of smokers. Latent clusters were found to vary systematically with individual difference factors relevant to smoking behavior and dependance (e.g., gender, ethnicity, education). Moreover, specific clusters were found to be predictive of smoking cessation success 6 months and 1 year post-treatment, highlighing the importance of social networks for understanding the dynamics of smoking behavior. FMM utilizing mixtures of multivariate t-distributions is a unique and robust alternative to traditional mixture modeling techniques commonly used in the behavioral sciences. The novel use of distributions robust to non-normal (t-distributions) data is a powerful way to examine the complex interactional nature of an individual’s social network and may serve as a useful tool for tobacco interventionists in order to target the social context of the smoker.